{"id":9060,"date":"2025-04-08T15:01:44","date_gmt":"2025-04-08T07:01:44","guid":{"rendered":"http:\/\/www.027-it.com\/?p=9060"},"modified":"2025-04-23T16:45:33","modified_gmt":"2025-04-23T08:45:33","slug":"%e5%ae%9e%e9%aa%8c%e5%ae%a4%e5%9c%a8%e7%a8%bb%e7%94%b0%e5%9c%9f%e5%a3%a4%e4%b8%ad%e9%95%89%e7%9a%84%e8%bf%81%e7%a7%bb%e8%bd%ac%e5%8c%96%e6%9c%ba%e5%88%b6%e6%96%b9%e9%9d%a2%e5%8f%96%e5%be%97%e8%bf%9b","status":"publish","type":"post","link":"http:\/\/www.027-it.com\/?p=9060","title":{"rendered":"\u5b9e\u9a8c\u5ba4\u5728\u7a3b\u7530\u571f\u58e4\u4e2d\u9549\u7684\u8fc1\u79fb\u8f6c\u5316\u673a\u5236\u65b9\u9762\u53d6\u5f97\u8fdb\u5c55"},"content":{"rendered":"

\u5728\u5177\u6709\u5468\u671f\u6027\u6df9\u6c34\/\u6392\u6c34\u7279\u5f81\u7684Cd\u6c61\u67d3\u7a3b\u7530\u571f\u58e4\u4e2d\uff0c\u786b\u9178\u76d0\u8fd8\u539f\u83cc\u5728\u6df9\u6c34\u671f\u95f4\u53ef\u5229\u7528\u786b\u9178\u76d0\u4f5c\u4e3a\u7535\u5b50\u53d7\u4f53\u751f\u6210\u8fd8\u539f\u6027\u786b\uff0c\u5176\u4e0eCd2+<\/sup>\u8fdb\u4e00\u6b65\u901a\u8fc7\u5316\u5b66\u6c89\u6dc0\u5f62\u6210\u76f8\u5bf9\u7a33\u5b9a\u7684CdS\uff0c\u964d\u4f4eCd\u7684\u751f\u7269\u6709\u6548\u6027\uff1b\u5728\u7a3b\u7530\u571f\u58e4\u6392\u6c34\u8fc7\u7a0b\u4e2d\uff0c\u597d\u6c27\u6761\u4ef6\u53ef\u5bfc\u81f4CdS\u88ab\u6c27\u5316\u6eb6\u89e3\uff0c\u589e\u52a0Cd\u7684\u751f\u7269\u6709\u6548\u6027\u3002\u5728\u8be5\u538c\u6c27-\u597d\u6c27\u8fc7\u7a0b\u4e2d\uff0cCd\u7684\u8fc1\u79fb\u8f6c\u5316\u884c\u4e3a\u4ea6\u53d7\u591a\u79cd\u73af\u5883\u56e0\u5b50\u5982Fe\u548c\u6709\u673a\u8d28\u7684\u5f71\u54cd\uff0c\u4f46\u5176\u73af\u5883\u5316\u5b66\u8fc7\u7a0b\u4e0e\u673a\u5236\u4ecd\u4e0d\u591f\u660e\u6670\u3002<\/p>\n

\u4e3a\u6b64\uff0c\u4e2d\u56fd\u79d1\u5b66\u9662\u5357\u4eac\u571f\u58e4\u7814\u7a76\u6240\u738b\u7389\u519b\u7814\u7a76\u5458\u56e2\u961f\u9996\u5148\u9488\u5bf9\u7a3b\u7530\u5e72\u6e7f\u4ea4\u66ff\u8fc7\u7a0b\u4e2dCdS\u7684\u5f62\u6210\u4e0e\u8f6c\u5316\u8fc7\u7a0b\u5f00\u5c55\u4e86\u6df1\u5165\u63a2\u7a76\u3002\u5728\u6709\u673a\u8d28\u548c\u65e0\u5b9a\u5f62\u94c1\u542b\u91cf\u8f83\u9ad8\u7684\u571f\u58e4\u4e2d\uff0c\u6df9\u6c34\u8fc7\u7a0b\u4f7f\u5f97\u786b\u9178\u76d0\u3001\u6709\u673a\u8d28\u4ee5\u53ca\u94c1\u6c27\u5316\u7269\u88ab\u5fae\u751f\u7269\u8fd8\u539f\uff0c\u5176\u4e2d\u751f\u6210\u7684\u8fd8\u539f\u6027\u786b\u4e0eCd\u7ed3\u5408\u5f62\u6210CdS\uff1b\u571f\u58e4\u843d\u5e72\u8fc7\u7a0b\u4e2d\uff0c\u8fd8\u539f\u6027\u6709\u673a\u8d28\u548cFe(II)\u53ef\u901a\u8fc7\u7c7b\u82ac\u987f\u53cd\u5e94\u5bfc\u81f4\u7f9f\u57fa\u81ea\u7531\u57fa\uff08\u2022OH\uff09\u7684\u751f\u6210\uff0c\u8fdb\u800c\u6c27\u5316CdS\uff0c\u589e\u52a0\u571f\u58e4\u4e2d\u53ef\u6eb6\u6001Cd\u7684\u6d53\u5ea6\uff08\u56fe1\uff09\u3002<\/p>\n

\"\"<\/a> \u56fe1. \u571f\u58e4\u5e72\u6e7f\u4ea4\u66ff\u8fc7\u7a0b\u4e2dCdS\u7684\u5f62\u6210\u4e0e\u8f6c\u5316\u8fc7\u7a0b<\/p>\n

\u4e3a\u8fdb\u4e00\u6b65\u7814\u7a76\u6709\u673a\u8d28\u3001\u94c1\u3001\u548c\u786b\u5982\u4f55\u5171\u540c\u8c03\u63a7Cd\u5728\u538c\u6c27-\u597d\u6c27\u8fc7\u7a0b\u4e2d\u7684\u5f52\u8d8b\uff0c\u7814\u7a76\u56e2\u961f\u5bf9\u5438\u9644\u4e8e\u6c34\u94c1\u77ff\u8868\u9762\u7684Cd\u5728\u786b\u5316-\u518d\u6c27\u5316\u8fc7\u7a0b\u4e2d\u7684\u8fc1\u79fb\u8f6c\u5316\u884c\u4e3a\u8fdb\u884c\u5bc6\u5207\u8ffd\u8e2a\uff0c\u5e76\u8003\u5bdf\u6709\u673a\u8d28\u7684\u5f71\u54cd\u3002\u7ed3\u679c\u8868\u660e\uff0c\u5728\u786b\u5316\u8fc7\u7a0b\u4e2d\uff0cS(-II)\u88ab\u5b8c\u5168\u6d88\u8017\uff0c\u90e8\u5206\u6c34\u94c1\u77ff\u88ab\u8fd8\u539f\u4e3aFe(II)\uff0c\u540c\u65f6\u6709\u673a\u8d28\u4ece\u6c34\u94c1\u77ff\u8868\u9762\u89e3\u5438\uff0c\u5438\u9644\u4e8e\u6c34\u94c1\u77ff\u8868\u9762\u7684Cd\u5219\u5b8c\u5168\u8f6c\u5316\u4e3aCdS\u3002\u518d\u6c27\u5316\u8fc7\u7a0b\u4e2d\uff0cFe(II)\u88ab\u6c27\u5316\u4e3aFe(III)\u6c27\u5316\u7269\uff0c\u6709\u673a\u8d28\u88ab\u91cd\u65b0\u5438\u9644\u3002\u4e0e\u6b64\u540c\u65f6\uff0c\u4e00\u90e8\u5206CdS\u53d1\u751f\u4e86\u6c27\u5316\uff0c\u8be5\u6c27\u5316\u884c\u4e3a\u4e3b\u8981\u7531Fe(II)\u6c27\u5316\u4ea7\u751f\u7684H2<\/sub>O2<\/sub>\u9a71\u52a8\uff0c\u00b7OH\u548cO2<\/sub>\u4ea6\u6709\u4e00\u5b9a\u8d21\u732e\uff0c\u7136\u800c\uff0c\u6709\u673a\u8d28\u901a\u8fc7\u6d88\u8017H2<\/sub>O2<\/sub>\u6291\u5236\u4e86CdS\u7684\u6c27\u5316\u8fc7\u7a0b\u3002\u4eceCdS\u4e2d\u91ca\u653e\u7684\u5927\u90e8\u5206Cd\u91cd\u65b0\u5438\u9644\u81f3Fe(III)\u6c27\u5316\u7269\u8868\u9762\uff0c\u5c11\u90e8\u5206\u91ca\u653e\u7684Cd\u5219\u5d4c\u5165Fe(III)\u6c27\u5316\u7269\u6676\u683c\u4e2d\u3002\u6b64\u5916\uff0c\u4e00\u90e8\u5206CdS\u88ab\u5305\u88f9\u4e8eFe(III)\u6c27\u5316\u7269\u805a\u96c6\u4f53\u5185\uff0c\u4f46\u6709\u673a\u8d28\u4e0eFe(III)\u6c27\u5316\u7269\u7684\u76f8\u4e92\u4f5c\u7528\u6291\u5236\u4e86\u60f0\u6027\u6001Cd\uff08\u5d4c\u5165\u6001Cd\u3001\u5305\u88f9\u6001CdS\uff09\u7684\u5f62\u6210\uff08\u56fe2\uff09\u3002<\/p>\n

\"\"<\/a><\/p>\n

\u56fe2. \u538c\u6c27-\u597d\u6c27\u8fc7\u7a0b\u4e2d\u6709\u673a\u8d28\u3001\u94c1\u548c\u786b\u5171\u540c\u8c03\u63a7Cd\u7684\u8fc1\u79fb\u8f6c\u5316\u884c\u4e3a<\/p>\n

\u00a0 \u00a0 \u4ee5\u4e0a\u7814\u7a76\u7ed3\u679c\u5bf9\u9884\u6d4b\u571f\u58e4\u5e72\u6e7f\u4ea4\u66ff\u8fc7\u7a0b\u4e2dCd\u7684\u751f\u7269\u6709\u6548\u6027\u4ee5\u53ca\u5f00\u5c55Cd\u6c61\u67d3\u4fee\u590d\u5177\u6709\u91cd\u8981\u6307\u5bfc\u610f\u4e49\uff0c\u76f8\u5173\u6210\u679c\u8fd1\u65e5\u53d1\u8868\u4e8eEnvironmental Science & Technology\u548cACS ES&T water\u3002\u8be5\u7814\u7a76\u5de5\u4f5c\u5f97\u5230\u56fd\u5bb6\u81ea\u7136\u79d1\u5b66\u57fa\u91d1\u6770\u51fa\u9752\u5e74\u57fa\u91d1\u7b49\u9879\u76ee\u7684\u8d44\u52a9\u3002<\/p>\n

\u8bba\u6587\u94fe\u63a51\uff1ahttp:\/\/pubs.acs.org\/doi\/10.1021\/acsestwater.4c01016<\/a><\/p>\n

\u8bba\u6587\u94fe\u63a52\uff1ahttp:\/\/pubs.acs.org\/doi\/10.1021\/acs.est.4c13365<\/u><\/p>\n","protected":false},"excerpt":{"rendered":"

\u7814\u7a76\u7ed3\u679c\u5bf9\u9884\u6d4b\u571f\u58e4\u5e72\u6e7f\u4ea4\u66ff\u8fc7\u7a0b\u4e2dCd\u7684\u751f\u7269\u6709\u6548\u6027\u4ee5\u53ca\u5f00\u5c55Cd\u6c61\u67d3\u4fee\u590d\u5177\u6709\u91cd\u8981\u6307\u5bfc\u610f\u4e49\uff0c\u6210\u679c\u8fd1\u65e5\u53d1\u8868\u4e8eEnvironmental Science & Technology\u548cACS ES&T water\u3002<\/p>\n","protected":false},"author":84,"featured_media":9062,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":"","_links_to":"","_links_to_target":""},"categories":[58],"tags":[],"class_list":["post-9060","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-58"],"_links":{"self":[{"href":"http:\/\/www.027-it.com\/index.php?rest_route=\/wp\/v2\/posts\/9060","targetHints":{"allow":["GET"]}}],"collection":[{"href":"http:\/\/www.027-it.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.027-it.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.027-it.com\/index.php?rest_route=\/wp\/v2\/users\/84"}],"replies":[{"embeddable":true,"href":"http:\/\/www.027-it.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=9060"}],"version-history":[{"count":1,"href":"http:\/\/www.027-it.com\/index.php?rest_route=\/wp\/v2\/posts\/9060\/revisions"}],"predecessor-version":[{"id":9063,"href":"http:\/\/www.027-it.com\/index.php?rest_route=\/wp\/v2\/posts\/9060\/revisions\/9063"}],"wp:featuredmedia":[{"embeddable":true,"href":"http:\/\/www.027-it.com\/index.php?rest_route=\/wp\/v2\/media\/9062"}],"wp:attachment":[{"href":"http:\/\/www.027-it.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=9060"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.027-it.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=9060"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.027-it.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=9060"}],"curies":[{"name":"wp","href":"http:\/\/api.w.org\/{rel}","templated":true}]}}